Examiner's comment
About a third of candidates were given Level 3 for this question. The key to answering this style of question well is to make sure all the information provided is used and to avoid contradictory statements, e.g. “structure contains carboxylic acid from IR” but then not present in final structure drawn, or a structure that doesn’t match the molecular formula given. A significant number of candidates did not include C=C despite being told in the question that it was “unsaturated and is a trans stereoisomer”, plus the C=C bond is shown in the IR and molecular formula needed unsaturation. The M+1 peak did confuse some candidates who then tried to add an extra H to final structure. It is very important that any structure given is feasible in terms of bonding; many candidates gave structures with C with 5 bonds (with both C=C and C=O attached), limiting them to achieving only L1. Some candidates gave a cis structure rather than trans. Other candidates ignored the O-H peak (from the carboxylic acid) in the IR spectrum, attributing this to a C-H bond as it was not as smooth or as prominent as they may have seen in other spectra. Some listed the bonds observed in the IR without linking to their position – this can easily be done by annotating the spectra. Many candidates had messy answers with lots of rough working which was then not crossed out – this made their answer very confusing. Note that no marks were given for just the empirical formula calculation and some attempted to produce a structure from the empirical formula without determining the Mr from the M+ peak in mass spectrum. This is an example of a good response which achieved L3 6 marks. Empirical and molecular formula are determined. Spectra have been annotated to aid their interpretation, but they have also included the key IR peaks as well as a MS fragment in their response. The correct structure for A is clearly drawn out. The response is clear and concise, with all information presented being relevant. If any of your students’ results are not as expected, you may wish to consider one of our post-results services. For full information about the options available visit the OCR website. We send a weekly roundup to tell you about important updates. You can also sign up for your subject specific updates. If you haven’t already, sign up here. Attend one of our popular CPD courses to hear directly from a senior assessor or drop in to a Q&A session. Most of our courses are delivered live via an online platform, so you can attend from any location. Please find details for all our courses on the relevant subject page on our website or visit OCR professional development. ExamBuilder is the question builder platform for a range of our GCSE, A Level, Cambridge Nationals and Cambridge Technicals qualifications. Find out more. ExamBuilder is free for all OCR centres with an Interchange account and gives you unlimited users per centre. We need an Interchange username to validate the identity of your centre's first user account for ExamBuilder. If you do not have an Interchange account please contact your centre administrator (usually the Exams Officer) to request a username, or nominate an existing Interchange user in your department. Review students' exam performance with our free online results analysis tool. It is available for all GCSEs, AS and A Levels and Cambridge Nationals. It allows you to: • review and run analysis reports on exam performance • analyse results at question and/or topic level • compare your centre with OCR national averages • identify trends across the centre • facilitate effective planning and delivery of courses • identify areas of the curriculum where students excel or struggle • help pinpoint strengths and weaknesses of students and teaching departments. Find out more. Post-results services Keep up-to-date OCR Professional Development Signed up for ExamBuilder?
Notes from the mark scheme and report
- empirical formula C2H3O, M+ 86 so C4H6O2
- broad O–H 2500–3300 and C=O 1630–1820 so carboxylic acid
- peak at 41 from loss of COOH
- CH3CH=CHCOOH drawn as trans isomer with justification (cis or trans accepted for structure)
- We have put together a range of online resources to support teaching of organic chemistry: https://www.ocr.org.uk/qualifications/as-a-level-gce-chemistry-a-h032-h432-from-2015/delivery- guide/module-cam04-module-4-core-organic-chemistry/delivery-guide-cadg012-organic- chemistry-as
Skills: M0.2 Use ratios, fractions and percentages; M3.1 Translate information between graphical, numerical and algebraic forms; M4.2 Visualise and represent 2-D and 3-D forms including 2-D representations of 3-D objects